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Application of Plants Extracts as Green Corrosion Inhibitors for Steel in Concrete - A review
Abstract
High requirements in protection of steel reinforcing bar (steel rebar) from corrosion are necessary since there are multi interaction of corrosive chemicals which cause early damage of concrete buildings. Corrosion of steel in concrete can destroy the concretes and reduce concrete strength. To protect rebar from corrosion, application of corrosion inhibitor is believed to have higher performance compared to other protection systems. To date, organic inhibitors have promising methods in steel rebar protection as they are environment-friendly, compatible with concrete, cost effective and applicable in any various concrete conditions. Thus, demands in using these inhibitors tend to increase significantly. This paper reviews the applications of green corrosion inhibitor specifically highlighted in protecting mechanisms, typical plants extracted, performance in corrosion protection, and classification of green corrosion inhibitors. The corrosion resistances of carbon steels in concrete protected by green inhibitors are in focus. As summary, it can be confidently notified that green corrosion inhibitors for steel in concrete will have a prospect to be used as corrosion prevention in the future with further improvements.
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Abbas, A.S.É.F. & T.I.Török,. (2018). Corrosion studies of steel rebar samples in neutral sodium chloride solution also in the presence of a bio-based (green) inhibitor, Int. J. Corros. Scale Inhib., 7(1), 38–47.
Abiola, O.K.N.C.O., E. E. Ebenso, and N. M. Nwinuka. (2007). Eco-friendly corrosion inhibitors: The inhibitive action of Delonix Regia extract for the corrosion of aluminium in acidic media. Anti-Corrosion Methods and Materials, 54, 219-224
Akshatha, G.B.G.J., Kumar & Pushpa. (2015). Effect of Corrosion Inhibitors in Reinforced Concrete. International Journal of Innovative Research in Science, Engineering and Technology. 4(8).
Alia, F.F., et al., (2017). High temperature oxidation in boiler environment of chromized steel. IOP Conference Series: Materials Science and Engineering. 257(1), 012086.
Amitha R. B. E, B.B., J. Basu., (2012). Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview. International Journal of Corrosion.
Asma, R., Y.P. Asmara, and C. Mokhtar. (2011). Study on the effect of surface finish on corrosion of carbon steel in CO2 environment. Journal of Applied Sciences, 11(11), 2053-2057.
Asmara, Y.P. A.G.M.Z.J.J., J.P. Siregar, D. Bachtiar, T. Kurniawan, Corrosion inhibition of carbon steel in oil and gas environments, International Journal of Advanced and Applied Sciences, 3 (5), 2016.
Asmara, Y.P., A. Juliawati, and A. Sulaiman. (2013). Mechanistic model of stress corrosion cracking (scc) of carbon steel in acidic solution with the presence of H2s. in IOP Conference Series: Materials Science and Engineering.
Asmara, Y.P., et al., (2016) Long Term Corrosion Experiment of Steel Rebar in Fly Ash-Based Geopolymer Concrete in NaCl Solution. International Journal of Corrosion, 5.
Asmara, Y.P., et al., (2016). Predicting Effects of Corrosion Erosion of High Strength Steel Pipelines Elbow on CO2-Acetic Acid (HAc) Solution. IOP Conference Series: Materials Science and Engineering. 114(1), 012128.
Asmara, Y.P., et al., (2017) Development of green vapour corrosion inhibitor. IOP Conference Series: Materials Science and Engineering, 257(1), 012089
Asmara, Y.P., et al., (2017). Application of response surface methodology method in designing corrosion inhibitor. IOP Conference Series: Materials Science and Engineering. 257(1), 012090.
Asmara, Y.P.a.M.I., (2011). Study combinations effects of HAc in H2S/CO2 corrosion. Journal of Applied Sciences, 11(10), 1821-1826.
Bentur, A., Diamond, Sidney, Berke, S. Neal. (1997) Steel Corrosion in Concrete: Fundamentals and civil engineering practice. Modern Concrete Technology, 201.
Bertolini, F.B. & T. Pastore. (2013). Behaviour of stainless steel in simulated concrete pore solution. British corrosion journal, 218-222.
Bhawsar, J.J., (2015). Experimental and computational studies of Nicotiana tabacum leaves extract as green corrosion inhibitor for mild steel in acidic médium. Engineering Journal. 54, 769-775.
Cabrini, M.F.F., S. Lorenzi, T. Pastore, & S. Pellegrini. (2015). Effect of Organic Inhibitors on Chloride Corrosion of Steel Rebars in Alkaline Pore Solution. Journal of Chemistry, 521507.
Cabrini, M.T.P. (2002). Effect of chemical substances on localized corrosion of steel in alkaline environments and concrete. in Frontiers in Corrosion Science and Technology: Proceedings of 15th International Corrosion Congress, Granada, 22-27, 2481-2488,
Darwin D, J.A.B., M. O’Reilly & L. Xing. (1974). Critical Chloride Corrosion Threshold for Galvanized Reinforcing Bars, A Report on Research Sponsored by the International Lead Zinc Research Organization, Inc. Project Code – ZC-24-2.
Ebenso, E.E.U.J.I., U. J. Ekpe et al. (2004). Corrosion inhibition studies of some plant extracts on aluminium in acidic medium, Transactions of the SAEST, 39(4), 117–123.
Elsener, B. (2001). Corrosion Inhibitors for Steel in Concrete: State of the Art Report,. EFC Publications, 35.
Eyu, D.H.E., C. Chukwuekezie, J. Idris, & Mohammad. (2013). Effect of Green Inhibitor on The Corrosion Behaviour of Reinforced Carbon Steel in Concrete. ARPN Journal of Engineering and Applied Sciences, 8(5).
Freire, L. X.R.N., M. F. Montemor, and M. J. Carmezim. (2009). Study of passive films formed on mild steel in alkaline media by the application of anodic potentials. Materials Chemistry and Physics, 114(2-3), 962–972.
Gaidis, J.M., (2004). Chemistry of corrosion inhibitors. Cement and Concrete Composites, 26(3), 181-189.
García Alonso, M.L.E., & J.M.Mirandaa. (2007). Corrosion behaviour of new stainless steels reinforcing bars embedded in concrete, Cement and Concrete Research. 37(10), 1463–1471.
Gouda, V.K, W.Y.H., (1970). Corrosion and Corrosion Inhibition of Reinforced Steel, Brit. Corrosion Journal, 5, 204-208
Gouda, V.K., (1970). Corrosion and corrosion inhibition of reinforcing steel. I. Immersed in alkaline solutions. British Corrosion Journal. 5(5), 198–203.
Hausmann, D.A. (1967). Steel corrosion in concrete—how does it occur? MAterials Protection. 6(11), 19-23.
Hazwan, M.H., A.A. Rahim, M. Nasir, and M. Ibrahim. (2016). The capability of ultra filtrated alkaline and organosolv oil palm (Elaeis guineensis) fronds lignin as green corrosion inhibitor for mild steel in 0.5 M HCl solution, Measurement, 78, 90-103
Hope, B.B. (1987). Chloride Corrosion Threshold in Concrete. ACI Mater, 306-314.
Hurley, M.F, J.R.S. (2006). Threshold Chloride Concentrations of Selected Corrosion-Resistant Rebar Materials Compared to Carbon Steel. Corrosion Science, 62, 892-904.
Jae Kim, M.K.K. & K. Yong Ann. (2016). The Influence of C3A Content in Cement on the Chloride Transport, Advances in Materials Science and Engineering.
James, M.G. (2004). Chemistry of corrosion inhibitors, Cement & Concrete Composites, 26, 181–189.
Jennifer L. Kepler, D.D., Carl E. Locke, Jr., (2000) Evaluation of Corrosion Protection Methods for Reinforced Concrete Highway Structures Structural Engineering and Engineering Materials SM Report No. 58, UNIVERSITY OF KANSAS CENTER FOR RESEARCH, INC. LAWRENCE, KANSAS.
Joshua, O.A.O., & O. Olubanke. (2015). Investigating prospects of Phyllanthus muellerianus as ecofriendly/sustainable material for reducing concrete steelreinforcement corrosion in industrial/microbial environment. Energy Procedia. 74, 1274 – 1281.
Kumar, V.R.S., and M. A. Quraishi., (2013). A Study on Corrosion of Reinforcement in Concrete and Effect of Inhibitor on Service Life of RCC. J. Mater. Environment Science, 4(5), 726-731.
Lisha, C.M.R., & G. Sunilaa. (2017). Corrosion Resistance of Reinforced Concrete with Green Corrosion. International Journal of Engineering Science Invention Research & Development; 3(11).
Loto, C.A, O.O.J., R.T. Loto, & A.P.I. Popoola. (2013). Inhibition Effect of Vernonia amygdalina Extract on the Corrosion of Mild Steel Reinforcement in Concrete in 3.5M NaCl Environment. Int. J. Electrochem. Sci., 8,11087 - 11100.
Magdalena, O.D.W., (2016). Organic substances as corrosion inhibitors for steel in concrete –an overview. Journal of Building Chemistry, 1, 42-53.
Nazanin, B. A.G., Salahandish, Effect of Orange Peel Extract on the Corrosion of Mild Steel in 1 M HCl Solution, 6th Conference on Thermal Power Plants, CTPP 2016 19-20 Jan. 2016, Iran University of Science and Technology, Tehran, Iran.
Njokua, D.M.A & Chidiebere, K.I.O., (2013). Corrosion inhibition of mild steel in hydrochloric acid solution by the leaf extract of Nicotiana tabacum. Adv Mater Corros. 1, 54-61.
Ormellese, M.M.B, F. Bolzoni, and T. Pastore. (2006). Corrosion inhibitors for chlorides induced corrosion in reinforced concrete structures. Cement and Concrete Research, 36(3), 536–547
Page, C.L., (1975). Mechanism of corrosion protection in reinforced concrete marine structures. Nature, 258(5535), 514-515.
Palanisamy, S.P.G.M., C. Kamal, & G. Venkatesh. (2016). Prosopis juliflora—A green corrosion inhibitor for reinforced steel in concrete. Research on Chemical Intermediates. 42(12), 7823–7840
Petterson, K. R.N.S. (1994). Chloride Threshold Value and the Corrosion Rate in Reinforced Concrete. Proceedings of the International Conference on Corrosion Protection of Steel in Concrete, Academic Press, Sheffield, 461.
Quraishi, M.A.V.K., B.N. Singh & S.K. Singh. (2012). Calcium Palmitate: A Green Corrosion Inhibitor for Steel in Concrete Environment. J. Mater. Environ. Sci. X(6), 1001-1008, 2028-2508.
Quraishi,M.A, D.K.Y.,and I. Ahamad. (2009). Green approach to corrosion inhibition by black pepper extract in hydrochloric acid solution. Open Corrosion Journal, 2, 56–60.
Quraishi,M.A.V.K., P.P. Abhilash & B.N. Singh. (2011). Calcium Stearate: A Green Corrosion Inhibitor for Steel in Concrete Environment. J. Mater. Environ. Sci. 2(4), 365-372, ISSN : 2028-2508.
Rosenberg, A.C.M.H.,& C. Andrade. (1989). Mechanisms of corrosion of steel in concrete, Materials science of concrete. The American Ceramic Society, 285-313.
Sangeetha M, S.R., T. Muthumegala, A. Krishnaveni. (2011). Green corrosion inhibitors-An Overview. Department of Chemistry (S&H), K.S.Rangasamy College of Technology,Tiruchengode,Tamil Nadu, India.
Sastri, V.C.i.P.A., John Wiley & Sons. (2001). UK, 619.
Shahid, M. (2011). Corrosion protection with eco-friendly inhibitors. Adv. Nat. Sci.: Nanosci. Nanotechnol, 2(04), 3001.
Shaymaa, A., Ali I. Al-Mosawi, Ali Amer & A. Hadi. (2017). Studying the Effect of Eco-addition Inhibitors on Corrosion Resistance of Reinforced Concrete. Bioprocess Engineering, 1(3): 81-86.
Söylev, T.A & M.G.R., (2008). Corrosion inhibitors for steel in concrete: state-of-the-art report. Construction and Building Materials, 22(4), 609-622.
Sulaiman, N.-A., & Abd-Razak. (2012). A Study of Using Allium Cepa (Onion) as Natural Corrosion Inhibitor in Industrial Chill Wastewater System. Research Journal of Chemical Sciences, 2231-606X, 2(5), 10-16.
Valcarce, M.V., (2008). Carbon steel passivity examined in alkaline solutions: the effect of chloride and nitrite ions. Electrochimica Acta, 53(15), 5007-5015.
Vermani, J., L. Kepler, D. Darwin, E. Carl E. Locke, Jr. Virmani, Y. P. Clear, K. C. and Pasko., (1983). Evaluation of Corrosio Protection Methods for Reinforced Concrete Highway Strcuture “Time to Corrosion of Reinforcing Steel in Concrete Slabs-Calcium Nitrite Admixture or Epoxy Coated Reinforcing Bars as Corrosion Protection Systems, Report No. FHWA-RD83-012, Federal Highway Administration, Washington, D.C.
DOI: https://doi.org/10.17509/ijost.v3i2.12760
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